There're two main steps to this: setting up Python and the packages stalkless uses, and then setting up the two R packages. It's not technically challenging, but it is fiddly. Sorry!
To run stalkless, just type python stalkless.py from the command prompt (Windows) or from Terminal (Mac/Linux). Under Windows, you may need to add Python to your Windows PATH.
This bit's easy! Install R (...you've already got it though, right?...). Then just run install.packages("Momocs", dependencies=TRUE).